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Germanium Safety Data Sheet (SDS)

SDS #: 363.1
Revision Date: February 25, 2016
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Germanium

Flinn Scientific, Inc. P.O. Box 219, Batavia, IL 60510 (800) 452-1261
Chemtrec Emergency Phone Number: (800) 424-9818
Signal Word
DANGER
SECTION 2 — HAZARDS IDENTIFICATION
Hazard class: Flammable solids (Category 1). Flammable solid (H228). Keep away from heat, sparks, open flames, and hot surfaces. No smoking (P210).

Hazard class: Skin and serious eye damage, corrosion or irritation (Category 2, 2A). Causes skin and serious eye irritation (H315+H319).

Hazard class: Specific target organ toxicity, single exposure; respiratory tract irritation (Category 3). May cause respiratory irritation (H335). Avoid breathing dust or fumes (P261).
Pictograms
SECTION 3 — COMPOSITION, INFORMATION ON INGREDIENTS
Component Name CAS Number Formula Formula Weight Concentration
Germanium

7440-56-4 Ge 72.59
SECTION 4 — FIRST AID MEASURES
Call a POISON CENTER or physician if you feel unwell.
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do so. Continue rinsing.
If on skin: Wash with plenty of water.
If swallowed: Rinse mouth. Call a POISON CENTER or physician if you feel unwell.
SECTION 5 — FIRE FIGHTING MEASURES
Noncombustible solid.
Flammable solid in dust form.
When heated to decomposition, may emit toxic fumes.
In case of fire: Use class D fire extinguisher or dry sand.
NFPA Code
None established
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Remove all ignition sources and water. Sweep up the spill, place in a sealed bag or container, and dispose. Ventilate area and wash spill site after material pickup is complete. See Sections 8 and 13 for further information.
SECTION 7 — HANDLING AND STORAGE
Flinn Suggested Chemical Storage Pattern: Inorganic Miscellaneous.
Store in a cool, dry place. Ground or bond container and receiving equipment (P240). Keep container tightly closed (P233). Use only in a hood or well-ventilated area (P271).
SECTION 8 — EXPOSURE CONTROLS, PERSONAL PROTECTION
Wear protective gloves, protective clothing, and eye protection (P280). Wash hands thoroughly after handling. Use only in a hood or well-ventilated area (P271).
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Dark to light gray powder or granules. Odorless.

Boiling point: 2830 °C
Melting point: 937.4 °C
Specific gravity: 5.323
Readily oxidizes at 600 - 700 °C
SECTION 10 — STABILITY AND REACTIVITY
Avoid contact with strong oxidizers and halogens.
Shelf life: Indefinite, if stored properly.
SECTION 11 — TOXICOLOGICAL INFORMATION
Acute effects: Irritant, coughing, chest pains, difficulty breathing.
Chronic effects: N.A.
Target organs: N.A.
ORL-RAT LD50: N.A.
IHL-RAT LC50: N.A.
SKN-RBT LD50: N.A.
SECTION 12 — ECOLOGICAL INFORMATION
Data not yet available.
SECTION 13 — DISPOSAL CONSIDERATIONS
Please review all federal, state and local regulations that may apply before proceeding.
Flinn Suggested Disposal Method #26a is one option.
SECTION 14 — TRANSPORT INFORMATION
Shipping name: Not regulated. Hazard class: N/A. UN number: N/A.
SECTION 15 — REGULATORY INFORMATION
TSCA-listed, EINECS-listed (231-164-3), RCRA code D001.
SECTION 16 — OTHER INFORMATION
This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. Flinn Scientific, Inc. makes no guarantee of the accuracy or completeness of the data and shall not be liable for any damages relating thereto. The data is offered solely for your consideration, investigation, and verification. The data should not be confused with local, state, federal or insurance mandates, regulations, or requirements and CONSTITUTE NO WARRANTY. Any use of this data and information must be determined by the science instructor to be in accordance with applicable local, state or federal laws and regulations. The conditions or methods of handling, storage, use and disposal of the product(s) described are beyond the control of Flinn Scientific, Inc. and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT(S).
Consult your copy of the Flinn Science Catalog/Reference Manual for additional information about laboratory chemicals.