Teacher Notes
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Teacher Notes![]() Chemical Bonding and the Properties of SolidsGeneral, Organic and Biological Chemistry KitMaterials Included In Kit
Aluminum shot, Al, 30 g
Aluminum strip, 6" x ½", 6* Hexane, C6H14, 100 mL Silicon dioxide (sand), SiO2, 30 g Sodium chloride (salt), NaCl, 10 g Stearic acid, C18H36O2, 10 g Sucrose (sugar), C12H22O11, 30 g Halite or rock salt (sodium chloride), 6 pieces* Pipets, Beral-type, 24 Quartz (silicon dioxide), 6 pieces* *Minerals for hardness testing Additional Materials Required
Acetone
Water, distilled or deionized Aluminum evaporating dishes or Pyrex® watch glasses, 12 Balances, 0.01-g precision, 3* Beakers, 150-mL, 3–5* Boiling stones Bunsen burners, 3–5* Candle (paraffin wax)† Conductivity testers, low-voltage, 3–5* Hot plates, 3–5* Mortars and pestles, ceramic, 5* Pennies and nails Reaction plates, 24-well, 12 Rock candy (sucrose)† Spatulas, 12 Stirring rods or toothpicks, 12 Test tubes, 13 x 100 mm, 60, or ceramic spot plates, 12 Test tube holders (clamps), 12 Test tube racks, 12 Wash bottles, 12 Wash bottle for acetone Wash bottle for distilled water Weighing dishes, 75 *May be shared, see Teaching Tips. †Optional minerals for hardness testing Safety PrecautionsHexane is a highly flammable liquid and vapor and a dangerous fire risk. Keep away from flames, heat and other sources of ignition. Hexane is an aspiration hazard—it may be fatal if swallowed and enters airways. It also causes skin and eye irritation and may cause drowsiness or dizziness if inhaled. Hexane is a suspected reproductive toxin. Do not use if you are pregnant. Cap the solvent bottle and work with hexane in a fume hood; make sure it is not used near or in the same area as the Bunsen burner used in step 13. Avoid contact of all chemicals with eyes and skin. Wear chemical splash goggles, chemical-resistant gloves and a lab coat or chemical-resistant apron. Please review current Safety Data Sheets for additional safety, handling and disposal information. Remind students to wash their hands thoroughly with soap and water before leaving the lab. DisposalConsult your current Flinn Scientific Catalog/Reference Manual for general guidelines and specific procedures, and review all federal, state and local regulations that may apply, before proceeding. The hexane solutions should be collected in a designated flammable organic waste container for licensed hazardous waste disposal according to Flinn Suggested Disposal Method #18b. All other solids and solutions may be disposed of in the trash or drain according to Flinn Suggested Disposal Methods #26a and b, respectively. Lab Hints
Teacher Tips
Further ExtensionsSupplementary Information {14030_Extensions_Table_1_Mohs Hardness Scale}
Hardness testing is important in materials science and engineering for steel and other alloys, ceramics and even plastics. Modern methods such as the Rockwell hardness test measure the depth or area of an indentation left by a diamond cone or a steel ball when a measured force is applied for a specified period of time.
Correlation to Next Generation Science Standards (NGSS)†Science & Engineering PracticesAsking questions and defining problemsPlanning and carrying out investigations Analyzing and interpreting data Engaging in argument from evidence Obtaining, evaluation, and communicating information Disciplinary Core IdeasMS-PS1.A: Structure and Properties of MatterMS-PS1.B: Chemical Reactions HS-PS1.A: Structure and Properties of Matter HS-PS1.B: Chemical Reactions Crosscutting ConceptsPatternsCause and effect Scale, proportion, and quantity Performance ExpectationsMS-PS1-1. Develop models to describe the atomic composition of simple molecules and extended structures. Answers to Prelab Questions
Sample DataLaboratory Report {14030_Data_Table_1}
*The average temperature of a Bunsen burner flame is greater than 1000 °C. Microburners will have a lower flame temperature. (Optional) Use this space to record observations of the hardness of mineral samples. A candle can be scratched with a fingernail (Mohs hardness = 2). ** See the Supplementary Information for a description of hardness testing and the Mohs hardness scale. Answers to Questions
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Student Pages
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Student Pages![]() Chemical Bonding and the Properties of SolidsGeneral, Organic and Biological Chemistry KitIntroductionLooking for patterns in the properties of different substances can help us understand how and why atoms join together to form compounds. What kinds of forces hold atoms together? How does the nature of the forces holding atoms together influence the properties of a material? Concepts
BackgroundGroups of atoms are held together by attractive forces that we call chemical bonds. The origin of chemical bonds is reflected in the relationship between force and energy in the physical world. Think about the force of gravity—in order to overcome the force of attraction between an object and the Earth, we have to supply energy. Whether we climb a mountain or throw a ball high into the air, we have to supply energy. Similarly, in order to break a bond between two atoms, energy must be added to the system, usually in the form of heat, light or electricity. The opposite is also true: whenever a bond is formed, energy is released. {14030_Background_Figure_1_Crystal structure of sodium chloride}
Covalent bonding represents another type of attractive force between atoms. Covalent bonds are defined as the net attractive forces resulting from pairs of electrons that are shared between atoms (the shared electrons are attracted to the nuclei of both atoms in the bond). A group of atoms held together by covalent bonds is called a molecule. Atoms may share one, two or three pairs of electrons to form single, double, and triple bonds, respectively. Substances held together by covalent bonds are usually divided into two groups based on whether individual (distinct) molecules exist. In a molecular solid, individual molecules in the solid state are attracted to each other by relatively weak intermolecular forces between the molecules. Covalent-network solids consist of atoms forming covalent bonds with each other in all directions. The result is an almost infinite network of strong covalent bonds—with no individual molecules. Covalent bonds may be classified as polar or nonpolar. The element chlorine, for example, exists as a diatomic molecule, Cl2. The two chlorine atoms are held together by a single covalent bond, with two electrons equally shared between the two identical chlorine atoms. This type of bond is called a nonpolar covalent bond. The compound hydrogen chloride (HCl) consists of a hydrogen atom and a chlorine atom that also share a pair of electrons between them. Because the two atoms are different, however, the electrons in the bond are not equally shared between the atoms. Chlorine has a greater electronegativity than hydrogen—it attracts the bonding electrons more strongly than hydrogen. The covalent bond between hydrogen and chlorine is an example of a polar bond. The distribution of bonding electrons in a nonpolar versus polar bond is depicted in Figure 2. Notice that the chlorine atom in HCl has a partial negative charge (δ–) while the hydrogen atom has a partial positive charge (δ+). {14030_Background_Figure_2_Nonpolar versus polar covalent bonds}
The special properties of metals compared to nonmetals reflect their unique structure and bonding. Metals typically have a small number of valence electrons available for bonding. The valence electrons appear to be free to move among all of the metal atoms, which must exist therefore as positively charged cations. Metallic bonding describes the attractive forces that exist between closely packed metal cations and free-floating valence electrons in an extended three-dimensional structure.
Experiment OverviewThe purpose of this experiment is to study the physical properties of common solids and to investigate the relationship between the type of bonding in a substance and its properties. The following physical properties will be studied:
Materials
Acetone
Aluminum shot or granules, Al, 0.5 g Aluminum strip† Hexane, C6H14, 5 mL Silicon dioxide (sand), SiO2, 0.2–0.3 g Sodium chloride (salt), NaCl, 0.2–0.3 g Stearic acid, C18H36O2, 0.2–0.3 g Sucrose (sugar), C12H22O11, 0.2–0.3 g Water, distilled Aluminum evaporating dish or Pyrex® watch glass Balance, 0.01-g precision* Beaker, 150-mL Boiling stones Bunsen burner* Candle (paraffin wax)† Conductivity tester, low-voltage* Halite or rock salt (sodium chloride)† Hot plate* Mortars and pestles, 5* Penny and nail† Pipets, Beral-type, 2 Quartz (silicon dioxide)† Reaction plate, 24-well Rock candy (sucrose)† Spatula Stirring rod or toothpicks Test tubes, Pyrex, small, 5, or ceramic spot plate Test tube holder (clamp) Test tube rack Wash bottle for acetone Wash bottle for distilled water Weighing dishes, 5 *May be shared. †Minerals for hardness testing (optional) Prelab Questions
Safety PrecautionsHexane is a highly flammable liquid and vapor and a dangerous fire risk. Keep away from flames, heat and other sources of ignition. Hexane is an aspiration hazard—it may be fatal if swallowed and enters airways. It also causes skin and eye irritation and may cause drowsiness or dizziness if inhaled. Hexane is a suspected reproductive toxin. Do not use if you are pregnant. Cap the solvent bottle and work with hexane in a fume hood; make sure it is not used near or in the same area as the Bunsen burner used in step 13. Avoid contact of all chemicals with eyes and skin. Wear chemical splash goggles, chemical-resistant gloves and a lab coat or chemical-resistant apron. Wash hands thoroughly with soap and water before leaving the lab. Procedure
Student Worksheet PDF |