Discovering Density
Student Laboratory Kit
Materials Included In Kit
Brass shot, medium size, 125 g Zinc shot, medium size, 500 g
Weighing dishes, 60
Additional Materials Required
Water Balance, electronic, 0.01-g precision, (1 for every 5 groups) Beaker, 100-mL Graduated cylinder, 25-mL
Paper towels Pen or marker Ruler, transparent
Prelab Preparation
Divide the brass shot into three samples, each approximately 35–40 g. Divide the zinc shot into 12 samples, also 35–40 g each. Carefully pour each sample into a 100-mL beaker.
Safety Precautions
Although the materials in this experiment are considered nonhazardous, follow all normal laboratory safety guidelines. Always wear safety glasses when working with glassware in the lab.
Disposal
The metal shot samples should be thoroughly dried and stored in their original labeled containers for repeat use. Have students decant most of the water from their graduated cylinders and then carefully pour their metal samples onto several layers of paper towels. Allow to air dry.
Lab Hints
- Enough materials are provided in this kit for 30 students working in pairs or for 15 groups of students. Three groups will use brass shot and 12 groups will use zinc shot. This is a Super Value Kit—all of the included materials can be dried and reused.
- The experimental work for this lab can reasonably be completed in one 45- or 50-minute lab period. If fewer than three balances are available for classroom use, the teacher may wish to pre-package metal samples to avoid long delays at the balances.
- Alternatively, if more balances are available, students may measure the mass of the graduated cylinder plus water plus metal sample directly on the balance. They can then record a running (cumulative) total of both mass and volume.
- In order to obtain two significant figures in each volume measurement, it is best to work with 8–14 g sample sizes in steps 3–4. It is important to keep the minimum mass above 8 g.
- Aluminum, brass, copper, and zinc shot all gave consistently accurate results using this method—percent errors in the density measurements ranged from 4 to 8%. (See Sample Data section.) If aluminum shot is used, the sample mass range must be reduced to 3–10 g.
- Metal turnings, metal sheet, and so-called “mossy zinc” gave less accurate results (percent errors ranged from 12 to 35%). Mossy zinc pieces, for example, have a large surface area and thus capture many small air bubbles. Air bubbles increase the apparent volume of the metal sample.
- The estimated uncertainty in volume measurements is similar in both 25- and 100-mL graduated cylinders (0.1 versus 0.2 mL, respectively). Thus, 100-mL cylinders may be used in place of the 25-mL cylinders if the latter are not available. Under these conditions, it is important to note the minimum mass of metal shot required to give precise volume measurements—it may be desirable to use samples having a larger mass.
- This lab has been written to compare experimental density results against literature values and to determine the accuracy of the results. The procedure can be adapted to measure the density of common objects (e.g., marbles, dice, hex nuts, bolts). An interesting extension might be to give different student groups different kinds or grades of nuts and bolts and ask students to evaluate their composition. (Are all nuts made of the same material?)
- Brass is an alloy (mixture of metals) and thus may have a variable composition and density. The value of the density for the brass shot included in this kit is 8.48 g/cm3.
Teacher Tips
- If students question the number of groups using “gold” samples compared to “silver,” suggest that “gold” is more rare and valuable than “silver.”
- It is not necessary to give students the definition and equations for density—let them discover the concept for themselves by collecting the data, recognizing the trend, and analyzing the results to find the quantitative relationship between mass and volume.
- Depending on the mathematical background of your students, it may be helpful to review the concept of slope and how it is measured. Students who have learned to use a graphing calculator may be encouraged to use the calculator to find the slope. Slope can also be found using a computer spreadsheet program. Be sure students include (0,0) as one of the data points.
- This experiment can be adapted to a discovery-based or inquiry lab. Start out by telling the story of Archimedes and the king’s gold crown. How did Archimedes prove the crown was gold or not? Give the students metal shot samples, an assortment of graduated cylinders of various sizes, and a challenge—measure the density of the metal. Expect a great deal of trial and error, since there are many variables that influence the reliability of the results. Students who start out with too large a graduated cylinder or too small a sample mass will discover that they need to modify their approach. The advantage of the inquiry approach is that students take it upon themselves to reduce experimental error, especially when they see other groups that “nail” the density. You may be surprised at the number of students who yell a modern version of “Eureka!”
- A common student misconception about density is that “bigger” objects are more dense. Students readily identify the more dense object when two objects are similar in overall size (volume). However, when they have to compare the densities of objects that are very different in size, they may think the bigger object is more dense. (Demonstrate this with a large block of wood and a small metal object—the small metal object sinks in water but the large wood block floats.)
Correlation to Next Generation Science Standards (NGSS)†
Science & Engineering Practices
Asking questions and defining problems Planning and carrying out investigations Using mathematics and computational thinking Analyzing and interpreting data
Disciplinary Core Ideas
MS-PS1.A: Structure and Properties of Matter HS-PS1.A: Structure and Properties of Matter
Crosscutting Concepts
Scale, proportion, and quantity Patterns Cause and effect
Performance Expectations
HS-ESS1-5: Evaluate evidence of the past and current movements of continental and oceanic crust and the theory of plate tectonics to explain the ages of crustal rocks. HS-ESS1-6: Apply scientific reasoning and evidence from ancient Earth materials, meteorites, and other planetary surfaces to construct an account of Earth’s formation and early history. HS-ESS2-7: Construct an argument based on evidence about the simultaneous coevolution of Earth’s systems and life on Earth. MS-ESS2-3: Analyze and interpret data on the distribution of fossils and rocks, continental shapes, and seafloor structures to provide evidence of the past plate motions.
Answers to Prelab Questions
- The volume of a metal cylinder was measured indirectly by water displacement three times. The following volume readings were recorded. Using Equation 1 from the Background section, determine the volume of the metal cylinder for each trial, and then calculate the average volume of the metal cylinder. Note: Since the volume of a solid is being measured, use the units cm3. Recall that 1 mL = 1cm3.
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{12603_Answers_Equation_3}
- The metal cylinder in Question 1 has a radius (r) = 1.05 cm and a height (h) = 3.32 cm. (a) Calculate the volume (V) of the metal cylinder (V = πr2h). (b) How does the average measured volume compare to the calculated (accepted) volume? (c) Use Equation 2 to calculate the percent error between the measured and accepted values for the volume of the cylinder.
{12603_PreLab_Equation_2}
V = πr2h = (3.14)(1.05 cm)2(3.32 cm) = 11.5 cm3 Accuracy is determined from the percent error:
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The accuracy of the volume measurements made by water displacement is 4%.
- “Bull’s-eye” drawings are often used to illustrate the concepts of accuracy and precision. Which drawing in Figure 2 suggests accurate but imprecise measurements of the quantity x? Which one illustrates precise but inaccurate measurements?
{12603_PreLab_Figure_2}
Drawing B suggests accurate but imprecise measurements of quantity x. The marks are all close to x, but not to each other. Drawing A shows precise measurements (they closely agree) that are inaccurate (they are not close to x).
Sample Data
Zinc Shot
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Brass Shot
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Aluminum Shot ( Shown for reference purposes only.)
{12603_Data_Table_5}
Graphing the Data Plot the mass and sample volume data for samples 1–4 on the following graph. Each sample will be represented by one point on the graph. Use the horizontal ( x) axis for the volume and the vertical ( y) axis for the mass. Label each axis—don’t forget the UNITS—and make sure the scale is clearly marked. Do NOT play “connect-the-dots” with the data points.
{12603_Data_Figure_4}
Answers to Questions
- Does it make sense that any trend or pattern in the mass and volume data should include (0,0) as a point? Explain your reasoning.
The point (0,0) should be included in all of the graphs, since a sample that has zero mass (does not exist) must also have zero volume.
- What kind of trend or pattern is obvious from the plotted graph of the mass and volume data? Is there a consistent relationship between the volume and mass of each sample? Explain.
As the mass of a sample increases, so does its volume in a regular or predictable manner. This direct relationship appears to be linear (i.e., a straight line can be drawn through all or most of the data points, including the (0,0) point).
- Based on your answers to Questions 1 and 2, draw a “best-fit” line through the data points. The best way to do this is to place a transparent ruler or straightedge at an angle over the data points—find the “best-fit” straight line that includes, or comes close to, as many points as possible.
See sample graphs. Note: Straight lines were drawn using a computer spreadsheet program to obtain the best-fit straight line through the data. If desired, a graphing calculator can be used. The option of incorporating this exercise should depend on the mathematical background and skill of the students.
- Calculate the slope of the “best-fit” line. Select two points—(x1,y1) and (x2,y2)—that are closest to the actual line. The slope (m) is calculated using Equation 5. Show all of your work! What are the units of the slope? What physical property is represented by the slope?
Note: Slope will vary depending on which data points are selected. For the sample data, slope was determined using a computer spreadsheet program.
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The slope represents the density of the metal.
- Are there are any data points that seem out of place in the set? Do you think all of the metal pieces in your sample set are made of the same metal? Explain.
Since all or most of the points are close to the line, it appears that all of the metal shot samples are made of the same material. The relationship between mass and volume appears to be a characteristic physical property that can be used to describe a metal sample. Note: It may not be unusual to obtain one or two “outlying” points that do not seem to fit on the straight line. (Generally speaking, these points should not be discarded unless they are off by more than two standard deviations from the average density.) In an honors or accelerated class you may choose to discuss various tests that can be used to discard data.
- Compare the calculated slope with that of another student group which used a differently colored metal (i.e., if your samples were silver, compare your data with a group that measured gold samples). Are the values of the slope the same? Why or why not?
Encourage students to compare their values of the slope with other students and to brainstorm about what the similarities and differences mean. Ideally, students should conclude that different samples are composed of different materials and that the slope is a characteristic physical property of a particular metal sample.
- Use the following information to determine the probable identity of your metal. What type of metal do you have?
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Answers will vary depending on the metals used.
- Assuming that the identification of your metal is valid, use Equation 2 from the Prelab Questions to calculate the percent error in your determination of the slope and the physical property it represents. The percent error measures the accuracy of your results. Comment on the accuracy of this procedure and discuss any possible sources of experimental error.
{12603_Answers_Table_7}
- (Optional) Density can be calculated directly by dividing the mass of an object by its volume. Using the mass and volume measurements recorded in the data table, calculate the density for each sample, the average density, and the difference between each density value and the average value. Comment on the precision of the density determination.
Sample calculations for zinc shot.
{12603_Answers_Table_8}
Density = 7.2 ±0.2 g/cm3. Excellent precision!
Sample calculations for brass shot.
{12603_Answers_Table_9}
Density = 8.6 ±0.3 g/cm3. Very good precision!
References
This activity was adapted from Flinn ChemTopic™ Labs, Vol. 1, Introduction to Chemistry; Cesa, I., Editor; Flinn Scientific, Inc; Batavia, IL (2006).
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