Teacher Notes
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Organic Rainbow![]() IntroductionObserve the hydrolysis reaction of an organic compound as the solution undergoes a series of vivid color changes. Concepts
MaterialsAcetone, CH3COCH3, 4 mL*
tert-Butyl chloride, (CH3)3CCl, 1 mL* Sodium hydroxide solution, NaOH, 1.0 M, 1 mL* Universal indicator solution, 4 mL* Water, distilled or deionized, 495 mL Graduated cylinder, 10-mL Graduated cylinder, 500-mL, or hydrometer cylinder Magnetic stirrer and stir bar Pipets, Beral-type, 2* Stirring rod Student worksheet* *Materials included in kit. Safety PrecautionsAcetone is flammable and a moderate fire risk. It is slightly toxic by ingestion and inhalation. tert-Butyl chloride is a moderate fire risk. It is moderately toxic by ingestion and inhalation. It is an eye irritant and is absorbed by the skin. Sodium hydroxide solution is a corrosive liquid and skin burns are possible. It is very dangerous to the eyes. Wear chemical splash goggles, chemical-resistant gloves and a chemical-resistant apron. Wash hands thoroughly with soap and water before leaving the laboratory. Please review current Safety Data Sheets for additional safety, handling and disposal information. DisposalPlease consult your current Flinn Scientific Catalog/Reference Manual for general guidelines and specific procedures, and review all federal, state and local regulations that may apply, before proceeding. The final solution may be flushed down the drain with excess water according to Flinn Suggested Disposal Method 26b. Any excess sodium hydroxide solution may be neutralized according to Flinn Suggested Disposal Method 10. Any excess tert-butyl chloride may be treated according to Flinn Suggested Disposal Method 27j. Procedure
Student Worksheet PDFTeacher Tips
Correlation to Next Generation Science Standards (NGSS)†Science & Engineering PracticesAsking questions and defining problemsDisciplinary Core IdeasMS-PS1.A: Structure and Properties of MatterMS-PS1.B: Chemical Reactions HS-PS1.A: Structure and Properties of Matter HS-PS1.B: Chemical Reactions Crosscutting ConceptsScale, proportion, and quantitySystems and system models Energy and matter Performance ExpectationsMS-PS1-1: Develop models to describe the atomic composition of simple molecules and extended structures. Answers to QuestionsIn this demonstration, the progress of the reaction between tert-butyl chloride and water is followed by adding an indicator and base to the reaction solution and observing the results.
Discussiontert-Butyl chloride, (CH3)3CCl, is an organic molecule that, while polar, is only slightly soluble in water. It is, however, soluble if it is first mixed with acetone, CH3COCH3. When this tert-butyl chloride/acetone mixture is added to water, the following reaction, called hydrolysis, occurs: {13886_Discussion_Equation_1}
In this demonstration, tert-butyl chloride and universal indicator solution are added to distilled water. As the tert-butyl reaction proceeds, a small amount of hydrochloric acid is produced, turning the solution from yellow to red, indicating a decrease in pH to 4. When sodium hydroxide is added, the small amount of acid produced is neutralized and the solution turns basic. The color changes to blue, indicating a change to a pH of 9. As the reaction proceeds, the hydroxide ions are consumed by the hydrochloric acid, lowering the pH of the solution. {13886_Discussion_Equation_2}
The pH continues to fall as the reaction proceeds, causing the universal indicator in solution to change to green, pH 7, to yellow, pH 6, to orange, pH 5, and finally red, pH 4. Adding additional sodium hydroxide will cause the reaction to start again and the color cycle to be repeated until all the tert-butyl chloride has reacted. ReferencesSpecial thanks to Penney Sconzo, Westminster Academy, Atlanta, GA, for bringing this demonstration to our attention. Recommended Products
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