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Bromoform Safety Data Sheet (SDS)

SDS #: 137.5
Revision Date: September 22, 2014
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Bromoform

Flinn Scientific, Inc. P.O. Box 219, Batavia, IL 60510 (800) 452-1261
Chemtrec Emergency Phone Number: (800) 424-9512
Signal Word
DANGER
SECTION 2 — HAZARDS IDENTIFICATION
Hazard Class: Acute toxicity, inhalation (Category 3). Toxic if inhaled (H331). Avoid breathing gas, mist, vapors or spray (P261).

Hazard Class: Acute toxicity, oral (Category 4). Harmful if swallowed (H302). Do not eat, drink or smoke when using this product (P270).

Hazard class: Skin and serious eye damage, corrosion or irritation (Category 2, 2A). Causes skin and serious eye irritation (H315+H319).

A solid below 47 °F.
Pictograms
SECTION 3 — COMPOSITION, INFORMATION ON INGREDIENTS
Component Name CAS Number Formula Formula Weight Concentration
Bromoform

Synonyms: Methyl tribromide
75-25-2 CHBr3 252.75
SECTION 4 — FIRST AID MEASURES
Call a POISON CENTER or physician (P311).
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing (P304+P340).
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do so. Continue rinsing(P305+P351+P338). If eye irritation persists eyes: Get medical advice or attention (P337+P313).
If on skin: Rinse cautiously with water for several minutes (P351).
If swallowed: Rinse mouth. Call a POISON CENTER or physician if you feel unwell (P301+P330+P312).
SECTION 5 — FIRE FIGHTING MEASURES
Nonflammable liquid.
When heated to decomposition, may emit toxic fumes.
In case of fire: Use a tri-class dry chemical fire extinguisher.
NFPA Code
None established
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Ventilate area. Contain the spill with sand or absorbent material and deposit in a sealed bag or container. See Sections 8 and 13 for further information.
SECTION 7 — HANDLING AND STORAGE
Flinn Suggested Chemical Storage Pattern: Organic #4. Store with ethers, ketones, and halogenated hydrocarbons.
Keep container tightly closed (P233). Use only in a hood or well-ventilated area (P271).
SECTION 8 — EXPOSURE CONTROLS, PERSONAL PROTECTION
Wear protective gloves, protective clothing, and eye protection. Wash hands thoroughly after handling (P264). Use only in a hood or well-ventilated area (P271).
Exposure guidelines: PEL/TLV 0.5 ppm (OSHA/ACGIH) Readily absorbed through the skin.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Colorless to yellow liquid. Chloroform-like color.
Soluble: Soluble in alcohol and many organic solvents.

Boiling point: 150-151 °C
Melting point: 8.3 °C
Specific gravity: 2.9
SECTION 10 — STABILITY AND REACTIVITY
Incompatible with bases, alkali metals, aluminum, magnesium, and their alloys.
Shelf life: Good, if stored properly. Keep bottle tightly closed and away from light.
SECTION 11 — TOXICOLOGICAL INFORMATION
Acute effects: Toxic, lachrymator, irritant.
Chronic effects: N.A.
Target organs: Liver and nerves.
ORL-RAT LD50: 1147 mg/kg
IHL-RAT LC50: N.A.
SKN-RBT LD50: N.A.
SECTION 12 — ECOLOGICAL INFORMATION
Data not yet available.
SECTION 13 — DISPOSAL CONSIDERATIONS
Please review all federal, state and local regulations that may apply before proceeding.
Flinn Suggested Disposal Method #27j is one option.
SECTION 14 — TRANSPORT INFORMATION
Shipping name: Bromoform. Hazard class: 6.1, Keep away from food. UN number: UN2515
SECTION 15 — REGULATORY INFORMATION
TSCA-listed, EINECS-listed (200-854-6), RCRA U225.
SECTION 16 — OTHER INFORMATION
This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. Flinn Scientific, Inc. makes no guarantee of the accuracy or completeness of the data and shall not be liable for any damages relating thereto. The data is offered solely for your consideration, investigation, and verification. The data should not be confused with local, state, federal or insurance mandates, regulations, or requirements and CONSTITUTE NO WARRANTY. Any use of this data and information must be determined by the science instructor to be in accordance with applicable local, state or federal laws and regulations. The conditions or methods of handling, storage, use and disposal of the product(s) described are beyond the control of Flinn Scientific, Inc. and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT(S).
Consult your copy of the Flinn Science Catalog/Reference Manual for additional information about laboratory chemicals.