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Nickel Sulfate Safety Data Sheet (SDS)

SDS #: 544
Revision Date: March 21, 2014
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Nickel Sulfate

Flinn Scientific, Inc. P.O. Box 219, Batavia, IL 60510 (800) 452-1261
Chemtrec Emergency Phone Number: (800) 424-10047
Signal Word
DANGER
SECTION 2 — HAZARDS IDENTIFICATION
Hazard class: Acute toxicity, oral (Category 3) and inhalation (Category 4). Toxic if swallowed (H301). Harmful if inhaled (H332). Do not eat, drink or smoke when using this product (P270). Avoid breathing dust or fumes (P261).

Hazard class: Skin corrosion or irritation (Category 2). Causes skin irritation (H315).

Hazard class: Sensitization, skin (Category 1). May cause an allergic skin reaction (H317).

Hazard class: Carcinogenicity (Category 1). May cause cancer (H350). Obtain special instructions before use (P201). Do not handle until all safety precautions have been read and understood (P202). Use personal protective equipment as required (P281). Nickel compounds are known human carcinogens by inhalation of dust (IARC-1).

Hazard class: Germ cell mutagenicity (Category 2). Suspected of causing genetic defects (H341).
Pictograms
SECTION 3 — COMPOSITION, INFORMATION ON INGREDIENTS
Component Name CAS Number Formula Formula Weight Concentration
Nickel sulfate, hexahydrate

Synonyms: Nickel(II) sulfate; Nickelous sulfate
10101-97-0 NiSO4•6H2O 262.87
SECTION 4 — FIRST AID MEASURES
If exposed or concerned: Get medical advice or attention (P308+P313).
If inhaled: Remove victim to fresh air in a position comfortable for breathing (P304+P340).
Eye: Immediately flush with fresh water for at least 15 minutes.
If on skin: Rinse cautiously with water for several minutes (P351).
If swallowed: Rinse mouth. Immediately call a POISON CENTER or physician (P301+P330+P310).
SECTION 5 — FIRE FIGHTING MEASURES
Noncombustible solid.
When heated to decomposition, may emit toxic fumes.
In case of fire: Use a tri-class dry chemical fire extinguisher.
NFPA Code
None established
SECTION 6 — ACCIDENTAL RELEASE MEASURES
When heated to decomposition, may emit fumes of Ni and NOx. entilate area. Contain the spill with sand or absorbent material and deposit in a sealed bag or container. See Sections 8 and 13 for further information.
SECTION 7 — HANDLING AND STORAGE
Flinn Suggested Chemical Storage Pattern: Inorganic #2. Store with acetates, halides, sulfates, sulfites, thiosulfates and phosphates. Store in a cool, dry place. Use only in a hood or well-ventilated area (P271).
SECTION 8 — EXPOSURE CONTROLS, PERSONAL PROTECTION
Wear protective gloves, protective clothing, and eye protection (P280). Wash hands thoroughly after handling (P264). Contaminated clothing should not be allowed out of the workplace (P272). Use only in a hood or well-ventilated area (P271).
Exposure guidelines: PEL 1 mg/m3 (OSHA), 0.1 mg/m3 (inhalable fraction) (ACGIH)
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Blue or emerald green crystals. Odorless.
Soluble: Water and alcohol
Loses 6H2O at 103 °C
Specific gravity: 2.031

SECTION 10 — STABILITY AND REACTIVITY
Avoid contact with strong oxidizers.
When heated to decomposition, emits toxic fumes of SOx.
Shelf life: Indefinite, if stored properly.
SECTION 11 — TOXICOLOGICAL INFORMATION
Acute effects: Toxic, sensitizer
Chronic effects: Dermatitis, mutagen, carcinogen as dust.
Target organs: Lungs
ORL-RAT LD50: N.A.
IHL-RAT LC50: N.A.
SKN-RBT LD50: N.A.
SECTION 12 — ECOLOGICAL INFORMATION
Data not yet available.
SECTION 13 — DISPOSAL CONSIDERATIONS
Please review all federal, state and local regulations that may apply before proceeding.
Flinn Suggested Disposal Method #27f is one option.
SECTION 14 — TRANSPORT INFORMATION
Shipping name: Not regulated. Hazard class: N/A. UN number: N/A
SECTION 15 — REGULATORY INFORMATION
TSCA-listed, EINECS-listed (232-104-9).
SECTION 16 — OTHER INFORMATION
This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. Flinn Scientific, Inc. makes no guarantee of the accuracy or completeness of the data and shall not be liable for any damages relating thereto. The data is offered solely for your consideration, investigation, and verification. The data should not be confused with local, state, federal or insurance mandates, regulations, or requirements and CONSTITUTE NO WARRANTY. Any use of this data and information must be determined by the science instructor to be in accordance with applicable local, state or federal laws and regulations. The conditions or methods of handling, storage, use and disposal of the product(s) described are beyond the control of Flinn Scientific, Inc. and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT(S).
Consult your copy of the Flinn Science Catalog/Reference Manual for additional information about laboratory chemicals.