Build a Solar Cell
Student Laboratory Kit
Materials Included In Kit
Ethyl alcohol, 5 mL Iodine/Potassium iodide electrolyte solution, I2/KI in propylene glycol, 1 mL Nitric acid, 0.001 M, 25 mL Titanium oxide, TiO2, nanocrystalline, 2 g Binder clips, 2
Candle, tealight Conductive glass, 1" x 3" plates, 2 Hibiscus petals, dried, 2 g Lens paper
Additional Materials Required
Water, distilled or deionized, 200 mL Beaker, 150-mL Cardboard box “canopy” Ceramic pad Cotton swab Forceps or tweezers Hot plate Microscope slide Mortar and pestle
Multimeter w/alligator clip leads Overhead projector Paper towels Petri dish Pipets, Beral-type, 3 Spatula Stirring rod Transparent tape, Magic™
Prelab Preparation
- Clean the conductive glass plates: Hold the plates with gloved hands or forceps and rinse with 2–3 mL of ethyl alcohol. Pat the plates dry with lens paper.
- Identify the conducting sides of the conductive glass plates: Set the multimeter to ohms and place the multimeter probes on the surface of the glass. The conductive side will register a reading of 10–30 ohms. Place all of the glass plates conductive side up on a clean paper towel.
- Dilute 1 mL of 0.1 M nitric acid to 100 mL with distilled or deionized water to prepare a 0.001 M nitric acid solution (pH 3). This solution will be used to prepare the titanium oxide suspension and may also be used to store the titanium oxide coated plates, if needed.
- Prepare a concentrated solution of natural hibiscus dye: Add 100 mL of distilled water to about 2 g of dried hibiscus in a 150-mL beaker and heat to boiling. Allow the mixture to steep for 15 minutes, then cool to room temperature and filter. The concentrated dye solution may be stored in the refrigerator overnight, if desired.
Safety Precautions
The solvent for the iodine/potassium iodide electrolyte solution is propylene glycol, a combustible organic liquid. Propylene glycol is a skin and eye irritant. The iodine is irritating to skin and eyes. Nanocrystalline titanium oxide is a fine dust and may be harmful if inhaled. Avoid breathing the fine particle dust and avoid contact of all chemicals with eyes and skin. The surface of the hot plate will be very hot. Place a HOT sign in front of the plate to warn observers that the hot plate is on. Wear chemical splash goggles, chemical-resistant gloves and a chemical-resistant apron. Please review current Safety Data Sheets for additional safety, handling and disposal information.
Disposal
Please consult your current Flinn Scientific Catalog/Reference Manual for general guidelines and specific procedures, and review all federal, state and local regulations that may apply, before proceeding. Excess titanium oxide suspension may be disposed of in the trash according to Flinn Suggested Disposal Method #26a. Excess iodine/potassium iodide solution may be reduced with excess sodium thiosulfate solution and disposed of according to Flinn Suggested Disposal Method #12a. After disassembly, the solar cell components may be rinsed with water and then disposed of in the trash according to Flinn Suggested Disposal Method #26a.
Teacher Tips
This kit contains enough materials to prepare four solar cells. For greatest efficiency, prepare the titanium oxide suspension as well as the hibiscus dye extract the day before the cells will be made. The cells may then be prepared in assembly line fashion—plan on about two hours for Parts A–C. There are two good stopping points if the complete setup and demonstration cannot be completed at one time. The undyed, titanium oxide–coated anode may be stored completely submerged in a dilute nitric acid solution in the dark. (Do not store the dyed electrode—some of the dye will rinse off in the solvent.) The graphite coated plates may also be stored in any safe location where they will not be accidentally disturbed. Alternatively, the anode and cathode may be clamped together and stored in the dark before the electrolyte solution is added. Finally, Parts A and B may be done by different groups as part of a collaborative class project.
- The solar cells are reusable and may be stored for several weeks in the dark. The cell voltage will decrease during storage, but the cell current is fairly stable. The electrolyte layer may be replenished by adding a few more drops of electrolyte solution as needed to ensure complete coverage.
- Conductive glass is produced by depositing a thin, transparent coating of fluorine-doped tin oxide (SnO2:F) on the glass by pyrolysis. Tin oxide is a wide-band-gap semiconductor.
- In a voltaic cell, the anode is considered the negative electrode, the cathode the positive electrode.
- Experiment with different dyes to see how they affect the solar cell. Extract fruits and flowers with water or ethyl alcohol and use the resulting dye solutions to stain the titanium oxide film. Nearly all fruits and flowers that are bright red, blue or purple contain a class of pigments or natural indicators called anthocyanins. Anthocyanins are derivatives of cyanidin with a varying numbers of hydroxyl (OH) and glucoside (OGl) groups attached to the aromatic rings in the structure (see Figure 5).
{13100_Tips_Figure_5_General structure of anthocyanin dyes}
- Commercial dye–sensitized solar cells utilize an organometallic ruthenium complex as the dye. The ligands in the coordination compound have been specially designed to coordinate with the titanium oxide coating and also to undergo efficient charge transfer to the titanium oxide conduction band.
- Construct an undyed solar cell and compare its electrical properties versus a dye-sensitized solar cell. The band gap energy for titanium oxide is 3–3.2 eV, corresponding to long-wavelength ultraviolet light (400 nm). An undyed titanium oxide solar cell will therefore require ultraviolet light for photoinitiation. In our experience, the maximum cell voltage for an undyed solar cell was about 0.25 V in sunlight, as opposed to 0.45 V for a dye-sensitized solar cell on an overhead projector. Theoretically, the maximum cell voltage is equal to the voltage difference between the Fermi level of the semiconductor and the standard reduction potential of the redox catalyst. For titanium oxide and iodine, the theoretical cell voltage is 0.9–1.0 V. An undyed solar cell may be converted to a DSC by disassembling the cell, rinsing the photoanode with ethyl alcohol, and then dyeing the titanium oxide as described in Part A, steps 12 and 13.
- Connect two cells in series and measure the combined voltage and current. The voltage is additive when cells are connected in series. The current, however, does not change when cells are connected in series—the same current flows through each cell in the series. Connect two cells in parallel and measure the combined voltage and current. The current is additive when cells are connected in parallel. The voltage should be the average of the individual voltages of each cell in the parallel circuit. Optimum performance is usually obtained with a parallel–series circuit (see Figure 6).
{13100_Tips_Figure_6_Parallel–series circuit}
Further Extensions
Alignment with AP Environmental Science Topics and Scoring Components Topic: Energy Resources and Consumption. Renewable Energy (Solar energy; solar electricity; hydrogen fuel cells; biomass; wind energy; small-scale hydroelectric; ocean waves and tidal energy; geothermal; environmental advantages/disadvantages). Scoring Component: 7-Energy Resources, Renewable Energy.
Correlation to Next Generation Science Standards (NGSS)†
Science & Engineering Practices
Asking questions and defining problems Developing and using models Constructing explanations and designing solutions Engaging in argument from evidence
Disciplinary Core Ideas
HS-PS1.A: Structure and Properties of Matter HS-PS1.B: Chemical Reactions HS-PS3.A: Definitions of Energy HS-ETS1.A: Defining and Delimiting Engineering Problems HS-ETS1.B: Developing Possible Solutions
Crosscutting Concepts
Cause and effect Scale, proportion, and quantity Systems and system models Energy and matter Structure and function
Performance Expectations
HS-PS1-1. Use the periodic table as a model to predict the relative properties of elements based on the patterns of electrons in the outermost energy level of atoms. HS-PS1-2. Construct and revise an explanation for the outcome of a simple chemical reaction based on the outermost electron states of atoms, trends in the periodic table, and knowledge of the patterns of chemical properties. HS-PS2-6. Communicate scientific and technical information about why the molecular-level structure is important in the functioning of designed materials. HS-PS3-3. Design, build, and refine a device that works within given constraints to convert one form of energy into another form of energy. HS-ETS1-1. Analyze a major global challenge to specify qualitative and quantitative criteria and constraints for solutions that account for societal needs and wants.
Sample Data
Typical results for nanocrystalline titanium oxide solar cells are summarized in the Answers to Questions section.
Results Table. Electrical Properties of Nanocrystalline Titanium Oxide Solar Cells
{13100_Answers_Table_1}
Answers to Questions
- What is the function of each of the following components in a dye-sensitized solar cell?
- Titanium oxide
Titanium oxide is a semiconductor. Electrons that are transferred from excited dye molecules enter the conduction band of titanium oxide. Electrons migrate from the anode to the cathode via an external circuit.
- Conductive glass
A conductive surface is needed for both electrodes to complete the external circuit for migration of electrons from the anode to the cathode through the solar cell.
- Natural dye
The dye absorbs visible light and acts as a “sensitizer” for the titanium oxide. Titanium oxide by itself does not absorb visible light.
- Iodine/iodide electrolyte solution
The iodine/iodide electrolyte solution acts as a redox catalyst to regenerate the reduced form of the dye at the anode.
- What are the advantages of dye-sensitized solar cells compared to conventional solar cells? What are the possible disadvantages?
Dye-sensitized solar cells do not require expensive, high-purity silicon for their manufacture. However, DSC are not as efficient as conventional solar cells.
- Predict how you would expect the voltage and the current produced by a DSC to change if the size of the solar cell were increased from 1" x 3" to 3" x 3".
The voltage of a DSC is an intrinsic property of the materials used in the solar cell and thus should not depend on the size of the cell. The current of a DSC should increase as the size of the solar cell increases, because there is a greater flow of electrons. Note: The current of a DSC is usually expressed in milliamps per square centimeter (mA/cm2).
Discussion
A solar cell, also called a photovoltaic cell, is a light-sensitive semiconductor device that uses the photoelectric effect to convert sunlight into electricity. A semiconductor is a material whose electrical conductivity increases with temperature or when irradiated with light. The increase in conductivity is due to electrons being promoted from the valence band to the conduction band. The energy difference is called the band gap energy and determines how much energy must be supplied for the material to conduct electricity.
Conventional solar cells contain a silicon diode as the semiconductor. The diode is created by joining n-type silicon (silicon doped with an impurity that has one more valence electron than silicon) to p-type silicon (silicon doped with an impurity that has one fewer valence electron than silicon). The different properties of the materials at the p-n junction give rise to a potential difference at the interface. Light striking the silicon surface excites electrons from the valence band to the conduction band and creates “electron-hole pairs.” Electrons move toward the positive side of the junction, “electron holes” toward the negative side, and the resulting flow of electrons generates an electric current. The main factor limiting the use of solid-state solar cells is cost. In order to obtain maximum efficiency in the conversion of sunlight into electricity, large, high-purity silicon crystals are required. At the present time, both the raw material and the manufacturing costs are prohibitive for widespread residential use.
In 1991, Michael Grätzel of the Swiss Federal Institute of Technology in Lausanne, Switzerland, reported a new type of solar cell called a dye-sensitized solar cell (DSC). Since the first DSC prototype was demonstrated more than 15 years ago, the technology has been commercialized to build solar panels for roofs and buildings. (Grätzel’s Swiss company is called Greatcell Solar.) The structure of a dye-sensitized solar cell separates the light-absorbing and electron-transfer functions of the solar cell, allowing both functions to be independently optimized.
Dye-sensitized solar cells are photoelectrochemical cells. The anode is nanocrystalline titanium oxide, a wide band-gap semi-conductor, and the cathode is carbon or platinum. An iodine/iodide electrolyte solution serves as a redox catalyst in the solar cell. Nanocrystalline titanium oxide (particle size 10–50 nm) is deposited as a thin film (about 40 microns thick) onto the surface of a conductive glass or polymer sheet. The coating is heated to anneal the titanium oxide particles and improve the electronic contact between the particles, and is then stained with a dye to make it sensitive to visible light. [The band gap energy of titanium oxide is about 3 eV, corresponding to ultraviolet light energy (about 400 nm). Thus, in the absence of a dye, titanium oxide requires ultraviolet light to initiate the photoelectric effect.] Using a nanocrystalline form of titanium oxide called anatase increases the effective surface area of the dye that is exposed to solar radiation and improves the efficiency of light and energy absorption. The maximum possible voltage for a titanium oxide–based solar cell using iodine as the redox catalyst is about 0.9 V—this is the difference between the Fermi level (conduction band) of TiO2 and the standard reduction potential of iodine.
The function of the dye in a dye-sensitized solar cell is similar to the light-harvesting reaction of chlorophyll during photosynthesis. Chlorophyll and other accessory pigments absorb visible light and the resulting excited state (high-energy) electrons travel down a series of intermediate electron acceptors with progressively lower reduction potentials. In a DSC, the dye absorbs visible light, which promotes an electron from the ground state to an excited state. The excited state electrons are transferred to the conduction band of titanium oxide, leaving oxidized dye molecules on the surface. The electrons migrate through the titanium oxide film and travel through the external circuit to the cathode. The dye is regenerated by accepting an electron from an iodide ion in the electrolyte solution. Iodide ions, acting as a redox catalyst, are regenerated by reduction of iodine at the cathode.
The components of a dye-sensitized solar cell are illustrated in the following schematic diagram (see Figure 7), and the working principles are summarized in steps 1–6:
{13100_Discussion_Figure_7_Design of a dye-sensitized solar cell}
- Dye molecule absorbs visible light.
- An electron in the dye is promoted to a “photoexcited state” (S*).
- S* transfers an electron into the conduction band (Fermi level, Ef) of TiO2.
- The oxidized dye accepts an electron from the redox catalyst (I–).
- Electrons migrate through the external circuit to the cathode.
- Iodine is reduced to iodide at the cathode, thus regenerating the redox catalyst.
In this kit, the sensitizer dye is a naturally occurring anthocyanin pigment isolated from dried hibiscus. Anthocyanins are highly colored pigments that are responsible for the red, blue, and purple colors in many different flowers and fruits. These pigments are normally present in all leaves but are usually masked by the green color of chlorophyll. In the fall, when the chlorophyll pigments become inactive, the red colors of the anthocyanins break through and are responsible for the bright orange and red fall foliage colors. The hibiscus extract prepared in this activity is a 1% solution—extraction of 2 g of dried hibiscus petals with 100 mL of water removes about 1 g of soluble substances. The absorption spectrum of a 1:10 diluted extract (approximately 0.1%) shows a strong absorbance maximum at 520 nm, as expected (see Figure 8).
{13100_Discussion_Figure_8_Visible spectrum of hibiscus extract}
References
Bohrmann-Linde, C.; Tausch, M., “Photogalvanic Cells for Classroom Investigations: A Contribution for Ongoing Curriculum Modernization,” J. Chem. Educ. 2003, 80, 1471–1473.
Grätzel, Michael, “Molecular Voltaics that Mimic Photosynthesis,” Pure Appl. Chem. 2001, 73, 459–467.
“Solar Cell Experiment,” The California NanoSystems Institute, University of California, Los Angeles, Science Outreach Program.
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